Synthesis and Characterization of Novel Water-Soluble Tetra-Substituted Zn(II) Phthalocyanine Containing Triazole and Galactose Moieties

Authors : Yasemin BAYĞU

Pages : 744-756

Doi:10.16984/saufenbilder.1266799

View : 86 | Download : 60

Publication Date : 2023-08-25

Article Type : Research Paper

Abstract :In this study, new water-soluble non-peripheral tetra-substituted zinc complex of phthalocyanine which is contain galactose moieties was synthesized. ZnPc-I was prepared from the galactose substituted dicyano compound by the cyclotetramerization reaction. This dicyano compound was synthesized by Click reaction between 3-insert ignore into journalissuearticles values(pent-4-yn-1-yloxy);phthalonitrile and 6-azido-6-deoxy1,2:3,4-di-O-isopropylidene-α-D-galactopyranose. ZnPc-II was obtained by hydrolysis of the protected isopropylidene groups in ZnPc-I in TFA and water mixture. The galactose linked Zninsert ignore into journalissuearticles values(II); phthalocyanine was achieved to dissolve in common polar solvents and water. All of the new compounds were characterized by elemental analysis, 1H NMR, 13C NMR, IR, UV–vis and MS spectral data.
Keywords : Zinc II, phthalocyanine, galactose, click reaction, water soluble phthalocyanine