BAZI YENİ DİNÜKLEER BAKIR(II) SCHİFF BAZI KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Authors : Bülent DEDE

Pages : 42-50

Doi:10.29233/sdufeffd.134638

View : 14 | Download : 8

Publication Date : 2008-06-01

Article Type : Research Paper

Abstract :Özet: Bu çalışmada. mononükleer bakırinsert ignore into journalissuearticles values(II); Schiff bazı kompleksine bakırinsert ignore into journalissuearticles values(II);, manganinsert ignore into journalissuearticles values(II);, kobaltinsert ignore into journalissuearticles values(II); ve nikelinsert ignore into journalissuearticles values(II); metal tuzlarının ilavesiyle dört yeni homo- ve heterodinükleer bakırinsert ignore into journalissuearticles values(II); kompleksi sentezlenmiştir. Sentezlenen tüm komplekslerin yapıları elementel analiz, manyetik sussebtibilite, molar iletkenlik, FT-IR ve ICP-OES çalışmalarıyla aydınlatılmıştır. Metal komplekslerin elementel analiz, stokiyometrik ve spektroskopik verileri, dinükleer bakırinsert ignore into journalissuearticles values(II); komplekslerde metal:ligand oranının 2:1 olduğunu ve bu komplekslerde bakırinsert ignore into journalissuearticles values(II); iyonlarının Schiff bazları ve oksimlerdeki azot atomlarıyla koordinasyona girdiğini göstermiştir. Anahtar kelimeler: Schiff baz, oksim, bakır kompleksleri, dinükleer SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL DINUCLEAR COPPERinsert ignore into journalissuearticles values(II); SCHIFF BASE COMPLEXES Abstract: In this study, four novel homo- and heterodinuclear copperinsert ignore into journalissuearticles values(II); complexes were synthesized by the addition of metal salts of copperinsert ignore into journalissuearticles values(II);, manganeseinsert ignore into journalissuearticles values(II);, cobaltinsert ignore into journalissuearticles values(II); and nickelinsert ignore into journalissuearticles values(II); to the mononuclear copperinsert ignore into journalissuearticles values(II); Schiff base complex. Synthesized all complexes were characterized by elemental analyses, magnetic susceptibility, molar conductivity, FT-IR and ICP-OES studies. Elemental analyses, stoichiometric and spectroscopic data of the metal complexes indicated that the metal:ligand ratio of dinuclear copperinsert ignore into journalissuearticles values(II); complexes were found to be 2:1 and those Cuinsert ignore into journalissuearticles values(II); ions are coordinated to the nitrogen atoms of the Schiff bases and oximes. Key words: Schiff base, oxime, copper complexes, dinuclear
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