N2O2 Tipi Schiff Bazı Ligandı ile Sentezlenen Cu(II) Kompleksinin X-Işını Yapısı ve Termal Özelliği

Authors : Ahmet Karahan, Alper Yardan, Yasemin Yahşi, Hülya Kara, Raif Kurtaran

Pages : 163-174

View : 13 | Download : 7

Publication Date : 2013-04-16

Article Type : Research Paper

Abstract :Cuinsert ignore into journalissuearticles values(II); kompleksinin X-ışınları moleküler yapısı 293 K`de tayin edildi. Cu insert ignore into journalissuearticles values(II); kompleksi monoklinik yapıda ve uzay grubu P21/n a= 12.4007insert ignore into journalissuearticles values(14);, b= 8.4476insert ignore into journalissuearticles values(9);, c= 20.0286insert ignore into journalissuearticles values(12); Ã…, β= 97.291insert ignore into journalissuearticles values(7);°. Termal davranışları diferansiyel termal analiz ve termogravimetrik analiz ile incelendi. Ayrıca Schiff bazı ligandının karakterizasyonunda elementel analiz, IR, UV-vis spektroskopisi, termal analiz, 1H-NMR ve 13C-NMR yöntemlerinden faydalanıldı. Anahtar kelimeler: Schiff bazı, Tek Kristal, X-ışınları analizi, Termal analiz The X-Ray Molecular Structure and Thermal Behaviour of Cu insert ignore into journalissuearticles values(II); Complex, Synthesis With N2O2 Type Schiff Base Ligand Abstract: The X-ray molecular structure of Cu insert ignore into journalissuearticles values(II); complex at 293 K has been determined. The Cu insert ignore into journalissuearticles values(II); complex, has been prepared and structurally and thermal characterized. The complex crystallizes in monoclinic space group P21/n with a= 12.407insert ignore into journalissuearticles values(14);, b= 8.4476insert ignore into journalissuearticles values(9);, c= 20.0286insert ignore into journalissuearticles values(12); Ã…, β= 97.291insert ignore into journalissuearticles values(7);°. The thermal behavior of the compound was investigated by differential thermal analysis and thermogravimetry. Additionally, Schiff base ligand also characterized by elemental analysis, IR, UV-vis spectroscopy, thermal analysis, 1H-NMR and 13C-NMR. Key words: Schiff base, Single crystal, X-ray analysis, Thermal analysis
Keywords : Schiff bazı, Tek Kristal, X ışınları analizi, Termal analiz