MAGNETIC MESOPOROUS SILICA NANOCOMPOSITES PREPARED WITH DIFFERENT SIZED Fe3O4: STRUCTURAL AND MAGNETIC PROPERTIES, CATALYTIC EFFECTS

Authors : Sezer ERDEM, Beyhan ERDEM, Ramis Mustafa ÖKSÜZOĞLU

Pages : 514-522

Doi:10.18038/aubtda.338384

View : 14 | Download : 9

Publication Date : 2018-03-31

Article Type : Research Paper

Abstract :The magnetically separable mesoporous silica nanocomposites were successfully prepared through a one-pot method including the co-condensation of tetraethoxysilane (TEOS) as silica precursor and 3-mercaptopropyl trimethoxysilane (MPTMS) as functionalizing agent accompanied with hydrogen peroxide for oxidation of mercapto groups and triblock copolymers as structure directing agent in the presence of ferromagnetic and superparamagnetic Fe 3 O 4 nanoparticles. By incorporating the superparamagnetic (near zero coercivity) Fe 3 O 4 nanoparticles to the mesoporous silica (SBA-15) and functionalizing with sulfonic acid groups instead of ferromagnetic Fe 3 O 4 nanoparticles, we developed versatile nanocomposite having superior properties with respect to magnetism, catalysis and porosity. Reducing the particle size of Fe 3 O 4 from the ferromagnetic regime to the superparamagnetic regime, the pore closure could be eliminated because of the more open pore as well as saving magnetic properties.
Keywords : Magnetic nanocomposites, Mesoporous silica, Esterification, Fe3O4, SBA 15