Combining selective sequential extractions, X-Ray Absorption Spectroscopy, and X-Ray Powder Diffraction for Cu (II) speciation in soil and mineral phases

Authors : Tatiana MİNKİNA, Dina NEVİDOMSKAYA, Alexander SOLDATOV, David PİNSKİİ, Fariz MİKAİLSOY, Victoria TSİTSUASHVİLİ, Tatiana BAUER, Victoria SHUVAEVA

Pages : 114-120

Doi:10.18393/ejss.286544

View : 32 | Download : 9

Publication Date : 2017-04-01

Article Type : Research Paper

Abstract :Interaction of Cu insert ignore into journalissuearticles values(II); ions with the matrix of soil and mineral phases of layered silicates was assessed by the Miller method of selective sequential fractionation and a set of synchrotron X-ray methods, including X-ray powder diffraction insert ignore into journalissuearticles values(XRD); and X-ray absorption spectroscopy insert ignore into journalissuearticles values(XANES);. It was shown that the input of Cu into Calcic Chernozem in the form of monoxide insert ignore into journalissuearticles values(CuO); and salt insert ignore into journalissuearticles values(Cuinsert ignore into journalissuearticles values(NO3);2); affected the transformation of Cu compounds and their affinity for metal-bearing phases. It was found that the contamination of soil with a soluble Cuinsert ignore into journalissuearticles values(II); salt increased the bioavailability of the metal and the role of organic matter and Fe oxides in the fixation and retention of Cu. During the incubation of soil with Cu monoxide, the content of the metal in the residual fractions increased, which was related to the possible entry of Cu in the form of isomorphic impurities into silicates, as well as to the incomplete dissolution of exogenic compounds at the high level of their input into the soil. A mechanism for the structural transformation of minerals was revealed, which showed that ion exchange processes result in the sorption of Cu insert ignore into journalissuearticles values(II); ions from the saturated solution by active sites on the internal surface of the lattice of dioctahedral aluminosilicates. Surface hydroxyls at the octahedral aluminum atom play the main role. X-ray diagnostics revealed that excess Cuinsert ignore into journalissuearticles values(II); ions are removed from the system due to the formation and precipitation of coarsely crystalline Cuinsert ignore into journalissuearticles values(NO3);insert ignore into journalissuearticles values(OH);3. 
Keywords : Cu II, ions, calcic chernozem, mineral phases, sequential fractionation, XRD, XANES Spectroscopy