Synthesis and Characterization of New Ferrocenyl and 3-methoxytolyl Dithiophosphonates

Authors : Ertuğrul Gazi SAĞLAM, Elif BULAT, Ayşe YILDIRIM

Pages : 183-191

Doi:10.17350/HJSE19030000270

View : 13 | Download : 7

Publication Date : 2022-09-28

Article Type : Research Paper

Abstract :In this study, perthiophosphonic acid anhydrides which are previously known insert ignore into journalissuearticles values(2,4-bisinsert ignore into journalissuearticles values(3-methoxytolyl);-1,3-dithia-2,4-diphosphetane-2,4-disulfide insert ignore into journalissuearticles values([insert ignore into journalissuearticles values(3-methoxytolyl);Pinsert ignore into journalissuearticles values(S);S);2], SAV-B1 reagent and 2,4-bisinsert ignore into journalissuearticles values(ferrocenyl);-1,3,2,4-dithiadiphosphetane-2,4-disulfide [insert ignore into journalissuearticles values(ferrocenyl);Pinsert ignore into journalissuearticles values(S);S);2], FcLR, Ferrocenyl Lawesson`s Reagent); react with alcohols to obtain new dithiophosphonic acids insert ignore into journalissuearticles values(3-methoxytolyl=insert ignore into journalissuearticles values(CH3);insert ignore into journalissuearticles values(OCH3);C6H3- and Xn=alkyl group insert ignore into journalissuearticles values(R); for SAV-B1, HXn; R1=3-pentyl-, HX1; R2=2-butyl-, HX2; R3=2-pentyl-, HX3 and Fc=Ferrocenyl- and Yn=allkyl or aryl group insert ignore into journalissuearticles values(R’); for FcLR, HYn; R’1=4-tert-cyclohexyl-, HY1; R’2=2-phenyl-1-propyl-, HY2);. These acids were then converted to ammonium salts insert ignore into journalissuearticles values([NH4][Xn], [NH4][Yn]);. The structures of ammonium salts were characterized by mass-insert ignore into journalissuearticles values(ESI);, FT-IR, 1H-, 13C- and 31P-NMR spectroscopy and elemental analysis.
Keywords : Ferrocenyl Dithiophosphonates, Dithiophosphonates, Dithiophosphonic Acid, Dithiadiphosphetanes disulfides, Perthiophosphonic Acid Anhydrides, SAV B1