Synthesis and characterization of non-symmetric tetradentate complexes of Zn(II), Co(II), and Cu(II)

Authors : Synthesis and characterization of non-sy Of

Pages : 263-268

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The non-symmetrical tetradentate Schiff-base H2L was obtained using the half-unit N-insert ignore into journalissuearticles values(1-hydroxy-2-acetophenone);-1-amino- 2-phenyleneimine insert ignore into journalissuearticles values(HL); with 2-hydroxyl-1-naphthaldehyde. ZnL, CoL, and CuL complexes were prepared and characterized by 1H-NMR, IR, electronic, and atomic absorption spectra. The single crystal X-ray structure of CuL was determined. Crystal data for CuL are triclinic space group P-1, a = 8.3933 insert ignore into journalissuearticles values(17); Å, b = 11.197 insert ignore into journalissuearticles values(2); Å, c = 13.381 insert ignore into journalissuearticles values(3); Å, a = 95.29 insert ignore into journalissuearticles values(3);°, b = 94.37 insert ignore into journalissuearticles values(3);°, g = 95.82 insert ignore into journalissuearticles values(3);°, and z = 2.
Keywords : Turk J Chem, 34, 2010, , 263 268 Turk J Chem, vol 34, iss 2