[Pd(Me-Xanthate)2]: Synthesis, Characterization, and X-Ray Structure

Authors : Saira SHAHZADI, Saqib ALI, Rehana Jabeen And M. Kaleem KHOSA

Pages : 307-312

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Potassium methyl xanthate and its complex [Pdinsert ignore into journalissuearticles values(Me-Xanthate);2] were synthesized at room temperature under stirring conditions. The ligand and the complex were characterized by elemental analysis, IR, NMR insert ignore into journalissuearticles values(1H, 13C); and XRD. NMR data revealed that potassium methyl xanthate acts as a bidentate specie and the complex exhibits 4-coordinated geometry in solution. In solid state, the palladium atom is coordinated to the 2 sulfur atoms of the xanthate ligand and the complex exhibits distorted square planar geometry.
Keywords : Palladium II, xanthate, spectroscopy, X ray structure