Crystal Structure of cis-bis(N,N-dimethyl-N`-benzoylthioureato)palladium(II)

Authors : Göktürk AVŞAR, Hakan ARSLAN

Pages : 281-286

View : 14 | Download : 7

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :In this study cis-bisinsert ignore into journalissuearticles values(N,N-dimethyl-N`-benzoylthioureato); palladiuminsert ignore into journalissuearticles values(II); is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943insert ignore into journalissuearticles values(1); Å, b = 11.713insert ignore into journalissuearticles values(1); Å, c = 15.345insert ignore into journalissuearticles values(1); Å, b = 93.90insert ignore into journalissuearticles values(1);°, and Dcalc = 1.616 g cm-1 for Z = 4. The Pdinsert ignore into journalissuearticles values(II); atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313insert ignore into journalissuearticles values(6); and 2.0211insert ignore into journalissuearticles values(16); Å, respectively.
Keywords : Complex, X ray structure, single crystal, N, N dimethyl N` benzoylthiourea