Synthesis and Spectral Characterization of Unsymmetric Organotin(IV) Derivatives

Authors : Saqib ALI, Moazzam H. BHATTI

Pages : 905-914

View : 11 | Download : 4

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Unsymmetric Organotininsert ignore into journalissuearticles values(IV); compounds of general formula R4-nSnR\primen have been synthesized by the reaction of corresponding organotininsert ignore into journalissuearticles values(IV); chlorides with n-hexyl magnesium bromide prepared in dry ether in situ, where R = CH3, n-C4H9, C6H5, C6H5CH2 and R\prime = n-C6H13. The reactions were carried out in dry toluene, refluxed for 6 h and the final products were purified through vacuum distillation. These compounds were characterized by multinuclear NMR insert ignore into journalissuearticles values(1H, 13C, 119Sn);, IR spectroscopy and mass spectrometry to predict their structures. All spectroscopic results support the four-coordination and tetrahedral geometry of the compounds.
Keywords : Unsymmetric organotin IV, compounds, multinuclear NMR, tetrahedral organotin IV, compounds