Mercuration Of Unsaturated p-Bromo Phosphonite and a-Chloro Phosphonate

Authors : Wüliam I. AWAD

Pages : 0-0

Doi:10.1501/Commub_0000000199

View : 11 | Download : 7

Publication Date : 1983-01-01

Article Type : Research Paper

Abstract :Diethyl insert ignore into journalissuearticles values(2- bromo -1- phenyl, vinyl); phosphonite and diethyl insert ignore into journalissuearticles values(1- chloro -1- phenyl, vinyl); phosphonate were allowed to react with mercuric acetate at different conditions inorder to eom» bine the organophosphorus and organomercuric compounds into one molecule and to study the effect of the vinyl group on the stability of P-C bond. Different mercurated products were ob- tained, some of them were due to cleavage of P-C bond with the formation of mercurated alip- hatic phosphonites and phosphonates and the others were formed through substitution and addi- tion reactions.
Keywords : Mercuration, Unsaturated, Phosphonite