Study of the Lithium Diffusion Properties of (Mgconilizn)O High Entropy Oxide as an Anode in Lithium-Ion Battery

Authors : Ersu LOKCU, Mustafa ANIK, Resat Can OZDEN

Pages : 77-81

Doi:10.55549/epstem.1068552

View : 16 | Download : 7

Publication Date : 2021-12-31

Article Type : Research Paper

Abstract :High-entropy oxide insert ignore into journalissuearticles values(HEO); based materials have recently significant attention as a conversion type anode material for lithium-ion batteries insert ignore into journalissuearticles values(LIBs); due to the high specific capacity, cycling stability and rate capability. However, the diffusion kinetics of HEO based anodes for conversion reactions, which occur during the charge and discharge processes have been not studied deeply in the literature. Therefore, the diffusion properties of lithium in the HEO electrodes need to be studied in detail. In this work, the insert ignore into journalissuearticles values(MgCoNiLiZn);O HEO anode was synthesized by conventional solid-state method. The obtained HEO sample was characterized structurally by X-ray diffraction insert ignore into journalissuearticles values(XRD); and scanning electron microscopy insert ignore into journalissuearticles values(SEM); techniques. The XRD analysis show that the HEO sample has been successfully synthesized with a single-phase rock-salt structure. The lithium diffusion properties of HEO sample were investigated by various electrochemical techniques including electrochemical impedance spectroscopy insert ignore into journalissuearticles values(EIS); and cyclic voltammetry insert ignore into journalissuearticles values(CV);.
Keywords : High entropy oxide, Lithium diffusion coefficient, SEM,