New Ways of Atomic Absorption Determination of some Elements with use of Heteropolycomplexes

Authors : A.b. VİSHNİKİN, M.e.a.al SHWAİYAT, E.v. VİSHNİKİNA, F.a. CHMİLENKO

Pages : 20-22

View : 10 | Download : 7

Publication Date : 2002-12-01

Article Type : Research Paper

Abstract :The reaction of 11-tungstophosphate with cobalt(II) has been used for indirect spectrophotometric and atomic absorption determination of phosphorus. Excess of cobalt is separated from mixed heteropolyanion with use of cation ion-exchange resin KU-2 in Na+-form. Cobalt can be determined after destruction of a heteropolyanion or as a complex with α-nitroso-β-naphtol, or on measuring of absorption of cobalt atoms using flame air-acetylene (λ=240,7 nm). The perspectives of this method has been shown for increasing of sensitivity and expansion of number of elements, which can be determined
Keywords : Determination of phosphorus, heteropolycomplex, indirect atomic absorption determination, ionexchange separation